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Here we pursue the biosynthesis of natural products, with the ultimate objectives of probing, understanding, and manipulating the genetic machinery of secondary metabolite biosynthesis in bacteria, fungi, and plants.
In the past, natural-products chemists have unearthed many compounds from natural sources. However, this process involves laborious purification steps to find a desired “grain of sand” in a metabolite beach. Recent genomics research has resulted in the deposition of a huge quantity of DNA sequencing data from a wide variety of organisms into publicly accessible databases. Using this insight from genome sequences, we are screening novel biosynthetic enzymes. This methodology, called “genome mining,” may offer an alternative route to identifying new compounds of biological origin.
Today, researchers’ understanding of polyketide biosynthesis has reached a point where we can now manipulate polyketide biosynthesis to generate libraries of “unnatural” natural products. Our research group is currently focused on studying type III polyketide synthases to produce “unnatural” forms of plant polyketides.